INTRODUCTION
Aluminium because of its low density, high tensile strength and
resistance to corrosion is widely used for the manufacture of airplanes,
automobiles, lawn furniture as well as for aluminium cans. Being
good conductor of electricity, it is also used for transmission
of electricity. Aluminium foil is used for wrapping cigarettes,
confectionery items, etc. Aluminium is also used for making utensils.
The recycling of aluminium cans and other aluminium products is
a very positive contribution to saving our natural resources. Most
of the recycled aluminium is melted and recast into other aluminium
metal products or used in the production of various aluminium compounds,
the most common of which are the alums. Alums are double sulphates
having general formula X2SO4.M2(SO4)3.24H2O
where,
X = monovalent cation such as Na+, K+, NH4+,
etc.
M = trivalent cation such as Al+3, Cr+3,
Fe+3, etc.
Some important alums and their names are given below:
Potash Alum: K2SO4.Al2(SO4)3.24H2O
Soda Alum Na2SO4.Al2(SO4)3.24H2O
Chrome Alum K2SO4.Cr2(SO4)3.24H2O
Ferric Alum (NH4)2SO4.Fe2(SO4)3.24H2O
Alums are isomorphous crystalline solids, which are soluble in
water. Potash alum is used in paper making, in fire extinguisher,
in foodstuffs and in purification of water. Soda alum is used in
baking powders and chrome alum is used in tanning leather and waterproofing
fabrics. Ferric alum is used in antiseptics. The shape of a potash
alum crystal is octahedral.

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